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Self-disclosure can provide psychological comfort and social support, but it also carries the risk of unintentionally revealing sensitive information, leading to serious privacy concerns. Research on self-disclosure in Chinese multimodal contexts remains limited, lacking high-quality corpora, analysis, and methods for detection. This work focuses on self-disclosure behaviors on Chinese multimodal social media platforms and constructs a high-quality text-image corpus to address this critical data gap. We systematically analyze the distribution of self-disclosure types, modality preferences, and their relationship with user intent, uncovering expressive patterns unique to the Chinese multimodal context. We also fine-tune five multimodal large language models to enhance self-disclosure detection in multimodal scenarios. Among these models, the Qwen2.5-omni-7B achieved a strong performance, with a partial span F1 score of 88.2%. This study provides a novel research perspective on multimodal self-disclosure in the Chinese context.