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Blind face restoration (BFR), which involves converting low-quality (LQ) images into high-quality (HQ) images, remains challenging due to complex and unknown degradations. While previous diffusion-based methods utilize feature extractors from LQ images as guidance, using raw LQ images directly as the starting point for the reverse diffusion process offers a theoretically optimal solution. In this work, we propose Pseudo-Hashing Image-to-image Schrödinger Bridge (P-I2SB), a novel framework inspired by optimal mass transport problems, which enhances the restoration potential of Schrödinger Bridge (SB) by correcting data distributions and effectively learning the optimal transport path between any two data distributions. Notably, we theoretically explore and identify that existing methods are limited by the optimality and reversibility of solutions in SB, leading to suboptimal performance. Our approach involves preprocessing HQ images during training by hashing them into pseudo-samples according to a rule related to LQ images, ensuring structural similarity in distribution. This guarantees optimal and reversible solutions in SB, enabling the inference process to learn effectively and allowing P-I2SB to achieve state-of-the-art results in BFR, with more natural textures and retained inference speed compared to previous methods.